{"id":4723,"date":"2017-12-06T16:45:53","date_gmt":"2017-12-06T15:45:53","guid":{"rendered":"https:\/\/www.ezn.de\/ezn-patent\/photo-switching-and-tuning-of-gas-transport-through-metal-organic-framework-membranes\/"},"modified":"2019-10-22T08:58:44","modified_gmt":"2019-10-22T06:58:44","slug":"photo-switching-and-tuning-of-gas-transport-through-metal-organic-framework-membranes","status":"publish","type":"ezn-patent","link":"https:\/\/www.ezn.de\/en\/ezn-patent\/photo-switching-and-tuning-of-gas-transport-through-metal-organic-framework-membranes\/","title":{"rendered":"Photo-switching and tuning of gas transport through metal-organic framework membranes"},"content":{"rendered":"<p>The proposed optical switching of the photoactive unit in the backbone of the linker molecules of the MOF as claimed in WO 2014015383 A1 and EP 13823026 is not practical since the whole crystal structure expands and shrinks upon optical switching like an accordion or like 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wavelengths is claimed. The metal-organic framework (MOF) membrane contains linker molecules with photo-switchable units in the side group of the backbone of the linker molecules. These photoactive units in the side groups can be switched reversibly into two conformations if enlightened with light of a specific wavelength. 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